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红土镍矿加压浸出高压釜结垢机理

冶金工程 • 矿业工程 • 化学化工

红土镍矿加压浸出高压釜结垢机理

泽森
晨晔
会泉
中国有色金属学报第34卷, 第11期pp.3766-3774纸质出版 2024-11-28
5500

加压酸浸技术是目前在红土镍矿镍钴提取工业上应用最为广泛的湿法提取技术,具有能耗低、碳排放量少、镍钴回收率高等优点。但在红土镍矿加压酸浸时,高压釜易结垢导致其有效容积减小、釜内流体流型改变、管线堵塞。为了明晰红土镍矿加压酸浸高压釜结垢生成机理,本文通过化学分析、MLA矿物自动定量分析系统、扫描电镜等手段对高压釜结垢的矿物组成、主要矿物颗粒、元素赋存状态、嵌布特征和粒度分布等矿物学特征进行了研究。结果表明:高压釜结垢主要以水合硫酸铝为骨架,包裹红土镍矿浸出渣中的赤铁矿、铬铁矿等矿相形成。镍、钴、锰、镁等金属元素通过吸附进入高压釜结垢,其中镍和钴主要是被含铁矿相吸附。

红土镍矿湿法冶金加压浸出结垢高压釜
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