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稀散金属高效分离提取及高纯化制备

冶金工程 • 矿业工程 • 化学化工

稀散金属高效分离提取及高纯化制备

学益
左伟
庆华
志鹏
红杰
中国有色金属学报第34卷, 第11期pp.3685-3712纸质出版 2024-11-28
10900

稀散金属被广泛应用于集成电路、航空航天、5G通信等领域,是现代工业、国防军工和战略性新兴产业不可或缺的支撑材料。本文综述了稀散金属复杂资源在高效富集、精细分离和高纯制备方面的研究动态及发展现状。我国稀散金属资源丰富,但在诸多方面仍值得进一步研究。在分离提取方面,需提升原生资源直收率并加强对二次资源的循环利用,实现分离提取的高效性、环保性和可持续性。在高纯化制备方面,需加强对基础理论方面的研究,进一步提高产品纯度和直收率。中南大学资源循环研究团队长期致力于稀散金属冶金基础理论及创新技术的研究,通过产学研联合攻关,取得了一系列原创性成果,通过理论创新、方法创新和装备创新,实现了稀散金属高效分离回收及高纯化制备的关键技术突破。面向未来,进一步开展并完善稀散金属高效分离提取及高纯化制备理论与实践创新,实现绿色、低碳、循环、智能及高值提取利用将是稀散金属冶金发展的主导方向。

稀散金属分离提取高纯化二次资源
REFERENCES
1ZHANG L G, XU Z M. A critical review of material flow, recycling technologies, challenges and future strategy for scattered metals from minerals to wastes[J]. Journal of Cleaner Production, 2018, 202: 1001-1025. doi:10.1023/a:1010650624155
2LI F Q, WANG P, CHEN W, et al. Exploring recycling potential of rare, scarce, and scattered metals: Present status and future directions[J]. Sustainable Production and Consumption, 2022, 30: 988-1000. doi:10.1023/a:1010650624155
3MEI Y R, GENG Y, CHEN Z J, et al. Ensuring the sustainable supply of semiconductor material: A case of germanium in China [J]. International Journal of Production Economics, 2024, 271: 109231. doi:10.1023/a:1010650624155
4王 岩, 李德先, 刘家军, 等. 基于大数据的中国稀散金属矿成矿规律定量研究[J]. 中国矿业, 2024, 33(4): 69-78. doi:10.1023/a:1010650624155
5周令治, 陈少纯. 稀散金属提取冶金[M]. 北京: 冶金工业出版社, 2008: 18-45. doi:10.1023/a:1010650624155
6李德先, 刘家军, 黄 凡, 等. 中国稀散金属矿资源概况[J]. 中国矿业, 2024, 33(4): 13-22, 1. doi:10.1023/a:1010650624155
7ZHU C T, GAO J, CHEN T, et al. Intrinsic thermal stability of inverted perovskite solar cells based on electrochemical deposited PEDOT[J]. Journal of Energy Chemistry, 2023, 83(8): 445-453. doi:10.1023/a:1010650624155
8SURVEY U S. Minerals Yearbook-Metals and Minerals [EB/OL]. [2024-06-28]. https://www.usgs.gov/centers/national-minerals-information-center/minerals-yearbook-metals-and-minerals. doi:10.1023/a:1010650624155
9HAN Z K, LIU Q C, OUYANG X, et al. Tracking two decades of global gallium stocks and flows: A dynamic material flow analysis[J]. Resources, Conservation and Recycling, 2024, 202: 107391. doi:10.1023/a:1010650624155
10张 伟, 李立清, 饶 帅, 等. 锌冶炼过程中提取镓的技术研究及其进展[J]. 工程科学学报, 2024, 46(4): 637-648. doi:10.1023/a:1010650624155
11RAJ P, PATEL M, KARAMALIDIS A. Chemically modified polymeric resins with catechol derivatives for adsorption, separation and recovery of gallium from acidic solutions[J]. Journal of Environmental Chemical Engineering, 2023, 11(5): 110790. doi:10.1023/a:1010650624155
12ZHENG Q, HE C L, MENG J J, et al. Behaviors of adsorption and elution on amidoxime resin for gallium, vanadium, and aluminium ions in alkaline aqueous solution[J]. Solvent Extraction and Ion Exchange, 2021, 39(4): 373-398. doi:10.1023/a:1010650624155
13QIN Z F, WANG S H, FAN L, et al. A hydrazine amidoxime crosslinked polyacrylonitrile resin for efficient extraction of gallium from vanadium-containing waste solution[J]. Chemical Engineering Science, 2023, 282: 119240. doi:10.1023/a:1010650624155
14LIU Z W, XU Z P, GUO X Y, et al. Gallium electrocrystallization process on SUS316 cathode in alkaline solution[J]. The Journal of Physical Chemistry C, 2023, 127(28): 13659-13666. doi:10.1023/a:1010650624155
15LIU Z W, GUO X Y, TIAN Q H, et al. Electrochemical behavior of gallium electrodeposition and inhibition of hydrogen evolution reaction in alkaline electrolyte[J]. Journal of Applied Electrochemistry, 2023, 53(4): 847-860. doi:10.1023/a:1010650624155
16FAN Y Y, LIU Y, NIU L P, et al. Reductive leaching of indium-bearing zinc ferrite in sulfuric acid using sulfur dioxide as a reductant[J]. Hydrometallurgy, 2019, 186: 192-199. doi:10.1023/a:1010650624155
17ZENG W Y, HUANG M Z, FU M L. Solid-phase extraction and separation of indium with P2O4-UiO-66-MOFs (di-2-ethylhexyl phosphoric acid-UiO-66-metal-organic frameworks)[J]. Journal of Environmental Sciences, 2023, 127: 833-843. doi:10.1023/a:1010650624155
18TIAN Q H, DONG B, GUO X Y, et al. Purification of crude indium by two-stage cyclone electrowinning[J]. Transactions of Nonferrous Metals Society of China, 2023, 33(10): 3185-3197. doi:10.1023/a:1010650624155
19KASHYAP V, TAYLOR P. Extraction and recovery of zinc and indium from residue rich in zinc ferrite[J]. Minerals Engineering, 2022, 176: 107364. doi:10.1023/a:1010650624155
20ZHANG F, WEI C, DENG Z G, et al. Reductive leaching of indium-bearing zinc residue in sulfuric acid using sphalerite concentrate as reductant[J]. Hydrometallurgy, 2016, 161: 102-106. doi:10.1023/a:1010650624155
21DELL'ERA A, CIRO Z, PASQUALI M, et al. Process parameters affecting the efficiency of indium electrowinning results from sulfate baths[J]. Hydrometallurgy, 2020, 193: 105296. doi:10.1023/a:1010650624155
22HUANG Y K, CHEN G Y, ZHANG Y F, et al. Separation of silicon and germanium from the chlorination distillation residue based on co-precipitation of sodium-aluminum-silicon[J]. Separation and Purification Technology, 2024, 350: 128015. doi:10.1023/a:1010650624155
23LI Y H, HE X H, YANG Y D, et al. High pressure acid leaching of low germanium bearing silica residue (GRS): Characterization of leach residue and mechanistic details of germanium leaching[J]. Hydrometallurgy, 2023, 216: 106015. doi:10.1023/a:1010650624155
24JIANG T, WANG P C, ZHANG T, et al. A novel solvent extraction system to recover germanium from H2SO4 leaching liquor of secondary zinc oxide: Extraction behavior and mechanism[J]. Journal of Cleaner Production, 2023, 383: 135399. doi:10.1023/a:1010650624155
25XU Y J, QU D K, XIA H Y, et al. Migration behavior of germanium and its related elements in zinc hydrometallurgy process[J]. Separation and Purification Technology, 2024, 330: 125467. doi:10.1023/a:1010650624155
26SONG L T, DI H K, LIANG M, et al. Ultrasonic-enhanced sulfuric acid leaching kinetics of high-grade germanium-containing materials[J]. Chemical Engineering and Processing - Process Intensification, 2022, 178: 109045. doi:10.1023/a:1010650624155
27LIANG D Q, WANG J K, WANG Y H, et al. Behavior of tannins in germanium recovery by tannin process[J]. Hydrometallurgy, 2008, 93(3): 140-142. doi:10.1023/a:1010650624155
28KAMRAN H, IRANNAJAD M, FORTUNY A, et al. Recovery of germanium from leach solutions of fly ash using solvent extraction with various extractants[J]. Hydrometallurgy, 2018, 175: 164-169. doi:10.1023/a:1010650624155
29TAN Z D, ZHEN Y, WEI C, et al. Organic phase modification of YW100 extraction system: Extraction of germanium using YW100+D2EHPA+N235[J]. Separation and Purification Technology, 2024, 329: 125175. doi:10.1023/a:1010650624155
30GAO Z, KONG X F, YANG B, et al. Extraction of scattered and precious metals from lead anode slime: A short review[J]. Hydrometallurgy, 2023, 220: 106085. doi:10.1023/a:1010650624155
31郭学益, 许志鹏, 田庆华, 等. 低温碱性熔炼分离富集铜阳极泥中的有价金属[J]. 中国有色金属学报, 2015, 25(8): 2243-2250. doi:10.1023/a:1010650624155
32GUO X Y, XU Z P, TIAN Q H, et al. Optimization on selenium and arsenic conversion from copper anode slime by low-temperature alkali fusion process[J]. Journal of Central South University, 2017, 24(7): 1537-1543. doi:10.1023/a:1010650624155
33LI D, GUO X Y, XU Z P, et al. Leaching behavior of metals from copper anode slime using an alkali fusion-leaching process[J]. Hydrometallurgy, 2015, 157: 9-12. doi:10.1023/a:1010650624155
34GUO X Y, XU Z P, LI D, et al. Recovery of tellurium from high tellurium-bearing materials by alkaline sulfide leaching followed by sodium sulfite precipitation[J]. Hydrometallurgy, 2017, 171: 355-361. doi:10.1023/a:1010650624155
35郭学益, 许志鹏, 李 栋, 等. 从碲渣中选择性分离与回收碲的新工艺[J]. 中国有色金属学报, 2018, 28(5): 1008-1015. doi:10.1023/a:1010650624155
36BLANCO-VINO W, ORDÓÑEZ J, HERNÁNDEZ P. Alternatives for copper anode slime processing: A review[J]. Minerals Engineering, 2024, 215: 108789. doi:10.1023/a:1010650624155
37HOU Y R, FU Z Q, LUO J, et al. Selective separation of rhenium from oxygen-pressure leach solution of molybdenite concentrate using modified D201 resin: Experiments and theoretical calculations[J]. Journal of Molecular Liquids, 2024, 408: 125371. doi:10.1023/a:1010650624155
38XIONG Y, XIE L S, ZHU L, et al. Superior adsorption of Re(Ⅶ) by anionic imprinted chitosan-silica composite: Adsorption performance, selectivity and mechanism study[J]. Journal of Industrial and Engineering Chemistry, 2022, 108: 344-355. doi:10.1023/a:1010650624155
39乔晋玺, 郭学益, 李 栋, 等. 铜污酸中铼的分离提取研究进展[J]. 工程科学学报, 2024, 46(3): 397-406. doi:10.1023/a:1010650624155
40WANG Y, WANG C Y. Recent advances of rhenium separation and enrichment in China: Industrial processes and laboratory trials[J]. Chinese Chemical Letters, 2018, 29(3): 345-352. doi:10.1023/a:1010650624155
41HAN G H, XUE Y B, LIU B B, et al. Deep separation of critical metals of Mo and Re from waste solution by stepwise precipitation flotation: Selective chelation underlying separation mechanism[J]. Separation and Purification Technology, 2023, 313: 123492. doi:10.1023/a:1010650624155
42邹铭金, 李 栋, 田庆华, 等. 从二次资源中分离回收镓的研究进展[J]. 有色金属科学与工程, 2020, 11(5): 45-51. doi:10.1023/a:1010650624155
43李 俊, 田庆华, 李 栋, 等. 从二次资源中回收锗的研究进展[J]. 有色金属工程, 2020, 10(1): 47-54. doi:10.1023/a:1010650624155
44曹 笑, 郭学益, 李 栋, 等. 从二次资源中回收铟的研究现状[J]. 金属材料与冶金工程, 2015, 43(2): 42-47. doi:10.1023/a:1010650624155
45LIU Z W, GUO X Y, TIAN Q H, et al. A systematic review of gold extraction: Fundamentals, advancements, and challenges toward alternative lixiviants[J]. Journal of Hazardous Materials, 2022, 440: 129778. doi:10.1023/a:1010650624155
46LIU Z W, TIAN Q H, GUO X Y, et al. Efficient separation and recovery of gallium from GaAs scraps by alkaline oxidative leaching, cooling crystallization and cyclone electrowinning[J]. Process Safety and Environmental Protection, 2024, 185: 467-479. doi:10.1023/a:1010650624155
47ZHAN L, XIA F F, XIA Y H, et al. Recycle gallium and arsenic from GaAs-based E-wastes via pyrolysis–vacuum metallurgy separation: Theory and feasibility[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(1): 1336-1342. doi:10.1023/a:1010650624155
48QIN R, CHEN J, BAI Y. High-efficiency stepwise recovery of gallium and rare earths from NdFeB waste by a hydrometallurgical process[J]. Separation and Purification Technology, 2024, 350: 127914. doi:10.1023/a:1010650624155
49ILLÉS I, KÉKESI T. The production of high-purity gallium from waste LEDs by combining sulfuric acid digestion, cation-exchange and electrowinning[J]. Journal of Environmental Chemical Engineering, 2023, 11(5): 110391. doi:10.1023/a:1010650624155
50YANG Y F, ZHENG X H, TAO T Y, et al. A sustainable process for selective recovery of metals from gallium-bearing waste generated from LED industry[J]. Waste Management, 2023, 167: 55-63. doi:10.1023/a:1010650624155
51MAAREFVAND M, SHEIBANI S, RASHCHI F. Recovery of gallium from waste LEDs by oxidation and subsequent leaching[J]. Hydrometallurgy, 2020, 191: 105230. doi:10.1023/a:1010650624155
52LI Z C, CHEN Z J, MA W H, et al. Efficient separation and recovery of valuable gallium and indium from gallium-based liquid metal waste[J]. Journal of Cleaner Production, 2023, 408: 137053. doi:10.1023/a:1010650624155
53LI Z C, CHEN Z J, MA W H, et al. Clean and efficient recovery of gallium-indium alloy from gallium-based liquid metal waste using a two-stage vacuum distillation method[J]. Vacuum, 2024, 221: 112884. doi:10.1023/a:1010650624155
54HU D, MA B Z, LI X, et al. Efficient separation and recovery of gallium and indium in spent CIGS materials[J]. Separation and Purification Technology, 2022, 282: 120087. doi:10.1023/a:1010650624155
55HU D, MA B Z, LI X, et al. Innovative and sustainable separation and recovery of valuable metals in spent CIGS materials[J]. Journal of Cleaner Production, 2022, 350: 131426. doi:10.1023/a:1010650624155
56GUSTAFSSON A, FOREMAN M, EKBERG C. Recycling of high purity selenium from CIGS solar cell waste materials[J]. Waste Management, 2014, 34(10): 1775-1782. doi:10.1023/a:1010650624155
57GÓMEZ M, GRIMES S, YANG L Y, et al. Novel resource-efficient recovery of high purity indium products: Unlocking value from end-of-life mobile phone liquid crystal display screens[J]. Journal of Environmental Chemical Engineering, 2023, 11(6): 111327. doi:10.1023/a:1010650624155
58ILLÉS I, NAGY S, KÉKESI T. The recycling of pure metallic indium from waste LCD screens by a combined hydro-electrometallurgical method[J]. Hydrometallurgy, 2022, 213: 105945. doi:10.1023/a:1010650624155
59CUI J Y, ZHU N W, LI Y, et al. Rapid and green process for valuable materials recovery from waste liquid crystal displays[J]. Resources, Conservation and Recycling, 2020, 153: 104544. doi:10.1023/a:1010650624155
60XU L, CHEN G J, ZHANG X F, et al. Waste ITO target recycling for efficient indium recovery through a closed-loop process[J]. Journal of Environmental Chemical Engineering, 2024, 12(2): 112136. doi:10.1023/a:1010650624155
61ZHANG X F, GE T, XU L, et al. Oxidative acid leaching of indium phosphide waste and recovery of indium metal by cementation with aluminum[J]. Hydrometallurgy, 2023, 221: 106109. doi:10.1023/a:1010650624155
62CHEN W S, CHANG B C, SHUAI C K. Improve subsequent leaching efficiency and extraction rate of germanium in optical fibre cables with pre-treatment[J]. IOP Conference Series: Materials Science and Engineering, 2020, 720(1): 012005. doi:10.1023/a:1010650624155
63CHEN W S, CHANG B C, CHEN Y J. Using ion-exchange to recovery of germanium from waste optical fibers by adding citric acid[J]. IOP Conference Series: Earth and Environmental Science, 2018, 159(1): 012008. doi:10.1023/a:1010650624155
64CHEN W S, CHANG B C, CHIU K L. Recovery of germanium from waste optical Fibers by hydrometallurgical method[J]. Journal of Environmental Chemical Engineering, 2017, 5(5): 5215-5221. doi:10.1023/a:1010650624155
65DHIMAN S, GUPTA B. Recovery of pure germanium oxide from Zener diodes using a recyclable ionic liquid Cyphos IL 104[J]. Journal of Environmental Management, 2020, 276: 111218. doi:10.1023/a:1010650624155
66RAFIEE P, GHASSA S, MOOSAKAZEMI F, et al. Recovery of a critical metal from electronic wastes: Germanium extraction with organic acid[J]. Journal of Cleaner Production, 2021, 315: 128223. doi:10.1023/a:1010650624155
67XU Z L, OKADA T, NISHIMURA F, et al. Recovery of palladium, cesium, and selenium from heavy metal alkali borosilicate glass by combination of heat treatment and leaching processes[J]. Journal of Hazardous Materials, 2017, 331: 171-181. doi:10.1023/a:1010650624155
68XU Z L, XU W G, LV Y, et al. Phase separation of molybdenum, cesium and selenium from the borosilicate glass containing simulated nuclear wastes under a CO2-rich heating atmosphere[J]. Journal of Nuclear Materials, 2019, 523: 216-222. doi:10.1023/a:1010650624155
69ZHANG X F, LIU D C, JIANG W L, et al. Application of multi-stage vacuum distillation for secondary resource recovery: Potential recovery method of cadmium telluride photovoltaic waste[J]. Journal of Materials Research and Technology, 2020, 9(4): 6977-6986. doi:10.1023/a:1010650624155
70ZHANG X F, HUANG D X, JIANG W L, et al. Selective separation and recovery of rare metals by vulcanization-vacuum distillation of cadmium telluride waste[J]. Separation and Purification Technology, 2020, 230: 115864. doi:10.1023/a:1010650624155
71邱叶红, 谢小林, 殷 亮, 等. 从碲化镉废料中回收碲的研究[J]. 化工技术与开发, 2021, 50(4): 49-51, 58. doi:10.1023/a:1010650624155
72FAN X X, YANG J Z, YANG N, et al. Experimental research on the pressure oxygen leaching rhenium of waste platinum-rhenium catalyst with low acid[J]. IOP Conference Series: Earth and Environmental Science, 2019, 218(1): 012066. doi:10.1023/a:1010650624155
73YE L G, OUYANG Z, CHEN Y M, et al. Recovery of rhenium from tungsten-rhenium wire by alkali fusion in KOH-K2CO3 binary molten salt[J]. International Journal of Refractory Metals and Hard Materials, 2020, 87: 105148. doi:10.1023/a:1010650624155
74卢晓锋, 朱纪念, 卢苏君, 等. 高温合金中铼金属回收制备高纯铼酸铵研究[J]. 稀有金属, 2021, 45(8): 972-979. doi:10.1023/a:1010650624155
75MAMO S, ELIE M, BARON M, et al. Leaching kinetics, separation, and recovery of rhenium and component metals from CMSX-4 superalloys using hydrometallurgical processes[J]. Separation and Purification Technology, 2019, 212: 150-160. doi:10.1023/a:1010650624155
76黎邹江, 李 栋, 许志鹏, 等. 旋流电积在有色冶金中的应用[J]. 有色金属科学与工程, 2019, 10(5): 1-7. doi:10.1023/a:1010650624155
77田庆华, 何志强, 郭学益, 等. 区域熔炼制备高纯金属研究进展[J]. 中国有色金属学报, 2023, 33(10): 3321-3336. doi:10.1023/a:1010650624155
78XU Z P, JIA L L, HE Z Q, et al. A review of preparing high-purity metals by vacuum distillation[J]. Transactions of Nonferrous Metals Society of China, 2024, 34(5): 1634-1654. doi:10.1023/a:1010650624155
79LIU Y, ZHENG Y J, SUN Z M. Preparation of high-purity tellurium powder by hydrometallurgical method[J]. Rare Metals, 2014, 33(4): 479-484. doi:10.1023/a:1010650624155
80SUN Z M, ZHENG Y J. Preparation of high pure tellurium from raw tellurium containing Cu and Se by chemical method[J]. Transactions of Nonferrous Metals Society of China, 2011, 21(3): 665-672. doi:10.1023/a:1010650624155
81LESZCZYŃSKA-SEJDA K, MAJEWSKI T, BENKE G, et al. Production of high-purity ammonium perrhenate for W-Re-Ni-Fe heavy alloys[J]. Journal of Alloys and Compounds, 2012, 513: 347-352. doi:10.1023/a:1010650624155
82姚 毅. 硫酸镓铵法生产高纯氧化镓实验[J]. 山东冶金, 2016, 38(4): 44-45. doi:10.1023/a:1010650624155
83张家润, 刘智勇, 刘志宏, 等. 高纯铼及其化合物的制备与应用研究进展[J]. 粉末冶金材料科学与工程, 2020, 25(4): 273-279. doi:10.1023/a:1010650624155
84ZHA G Z, YANG B, LUO H, et al. Innovative green approach for the selective extraction of high-purity selenium from hazardous selenium sludge[J]. Separation and Purification Technology, 2021, 266: 118536. doi:10.1023/a:1010650624155
85HUANG D X, JIANG W L, XU B Q, et al. Purification of metallurgical-grade crude tellurium based on viscous distillation and gas-phase separation[J]. Transactions of Nonferrous Metals Society of China, 2024, 34(3): 1037-1048. doi:10.1023/a:1010650624155
86ZHANG X W, MIAO R Y, CHEN D H, et al. Numerical simulation during vacuum sublimation purification of metal Tm (Ⅰ): Model foundation and validation[J]. Journal of Rare Earths, 2013, 31(2): 180-185. doi:10.1023/a:1010650624155
87EZHEIYAN M, SADEGHI H. Simulation for purification process of high pure germanium by zone refining method[J]. Journal of Crystal Growth, 2017, 462: 1-5. doi:10.1023/a:1010650624155
88WANG S, FANG H S, JIN Z L, et al. Integrated analysis and design optimization of germanium purification process using zone-refining technique[J]. Journal of Crystal Growth, 2014, 408: 42-48. doi:10.1023/a:1010650624155
89SPIM J, BERNADOU M, GARCIA A. Numerical modeling and optimization of zone refining[J]. Journal of Alloys and Compounds, 2000, 298: 299-305. doi:10.1023/a:1010650624155
90LIU Y, MOSS R, DOST S. A computational thermal analysis for the zone-refining processes of Cd and Te[J]. Journal of Crystal Growth, 2006, 293(1): 146-156. doi:10.1023/a:1010650624155
91HOU J, PAN K, TAN X. Preparation of 6N, 7N high-purity gallium by crystallization: Process optimization[J]. Materials, 2019, 12(16): 2549. doi:10.1023/a:1010650624155
92YOON J, YANG J. Study of refining and purification processing of gallium metal as a raw materials for compound semiconductor[J]. ECS Meeting Abstracts, 2020, (25): 1799. doi:10.1023/a:1010650624155
93DING C Y, JIANG L, LI Z S, et al. Numerical simulation and experimental verification of axial-directional crystallization purification process for high-purity gallium[J]. Transactions of Nonferrous Metals Society of China, 2020, 30(12): 3404-3416. doi:10.1023/a:1010650624155
94LEE H, YEOL Y, JO J, et al. The manufacturing technology of grade 6N high-purity indium metal for compound semiconductor[J]. Materials Today: Proceedings, 2021, 42: 304-311. doi:10.1023/a:1010650624155
95郭学益, 徐润泽, 田庆华, 等. H2O2/SO2催化还原六价硒及硒单质形成机理[J]. 中国有色金属学报, 2017, 27(11): 2370-2378. doi:10.1023/a:1010650624155
96郭学益, 许志鹏, 李 栋, 等. 一种协同氧化浸出碲渣中碲的方法, CN105925811B[P]. 2017-07-14. doi:10.1023/a:1010650624155
97TIAN Q H, LI J, GUO X Y, et al. Efficient electrochemical recovery of tellurium from spent electrolytes by cyclone electrowinning[J]. Journal of Sustainable Metallurgy, 2021, 7(1): 27-45. doi:10.1023/a:1010650624155
98XU Z P, GUO X Y, TIAN Q H, et al. Electrodeposition of tellurium from alkaline solution by cyclone electrowinning[J]. Hydrometallurgy, 2020, 193: 105316. doi:10.1023/a:1010650624155
99HONG J B, XU Z P, LI D, et al. A pilot study: Efficient electrowinning of tellurium from alkaline solution by cyclone electrowinning technology[J]. Hydrometallurgy, 2020, 196: 105429. doi:10.1023/a:1010650624155
100GUO X Y, MA Z C, LI D, et al. Recovery of Re(VII) from aqueous solutions with coated impregnated resins containing ionic liquid Aliquat 336[J]. Hydrometallurgy, 2019, 190: 105149. doi:10.1023/a:1010650624155
101GUO X Y, MA Z C, LI D, et al. Coated impregnated resin containing Alamine 336 for the selective adsorption of ReO4—From sulfuric acid solutions[J]. Journal of Molecular Liquids, 2020, 297: 111901. doi:10.1023/a:1010650624155
102MA Z C, GUO X Y, LI D, et al. Adsorption of Re(VII) from sulfuric acid solutions by coated impregnated resins containing TBP[J]. Separation Science and Technology, 2020, 55(18): 3320-3328. doi:10.1023/a:1010650624155
103GUO X Y, MA Z C, LIU G W, et al. Adsorption of Re(VII) by coated solvent-impregnated resins containing Alamine 304-1 from sulfuric acid solutions[J]. Rare Metals, 2020, 39(8): 942-950. doi:10.1023/a:1010650624155
104郭学益, 石 靖, 易 宇. 高砷烟尘碱性浸出液氧化结晶制备砷酸钠[J]. 矿冶工程, 2015, 35(3): 83-86. doi:10.1023/a:1010650624155
105LIU Z W, GUO X Y, XU Z P, et al. Recent advancements in aqueous electrowinning for metal recovery: A comprehensive review[J]. Minerals Engineering, 2024, 216: 108897. doi:10.1023/a:1010650624155
106XU Z P, LIU Z W, GUO X Y, et al. Gallium recovery by cyclone electrowinning from alkaline electrolyte with titanium cathode[J]. Transactions of Nonferrous Metals Society of China, 2024, 34(3): 1027-1036. doi:10.1023/a:1010650624155
107LIU Z W, TIAN Q H, GUO X Y, et al. Pulse cyclone electrowinning of gallium recovery for higher current efficiency and lower energy consumption[J]. Separation and Purification Technology, 2023, 326: 124801. doi:10.1023/a:1010650624155
108李 栋, 黎邹江, 许志鹏, 等. 一种从高铁含铟废液中回收铟的方法: CN113373323B[P]. 2022-12-06. doi:10.1023/a:1010650624155
109郭学益, 张 磊, 田庆华, 等. 一种制备高纯碲的设备及方法: CN110894065B[P]. 2023-04-07. doi:10.1023/a:1010650624155
110郭学益, 徐润泽, 李 栋, 等. 一种横向连续真空蒸馏装置: CN206843560U[P]. 2018-01-05. doi:10.1023/a:1010650624155
111许志鹏, 张 磊, 田庆华, 等. 一种靶向涡流强化区域熔炼制备高纯碲的区熔装置及方法: CN114590783B[P]. 2023-04-11. doi:10.1023/a:1010650624155
112田庆华, 秦 红, 郭学益, 等. 镓提纯装置及方法: CN110938755B[P]. 2021-06-11. doi:10.1023/a:1010650624155
113何志达, 文崇斌, 黄杰杰, 等. 一种高纯碲的制备方法: CN112758901B[P]. 2023-08-01. doi:10.1023/a:1010650624155
114许志鹏, 邹铭金, 郭学益, 等. 一种粗镓的电解精炼装置及电解精炼方法: CN113549955B[P]. 2022-05-20. doi:10.1023/a:1010650624155
115郭学益, 张 磊, 田庆华, 等. 高纯铟的区熔装置及区熔方法: CN110923479B[P]. 2024-03-26. doi:10.1023/a:1010650624155
116赵青松, 牛晓东, 黄幸慰, 等. 区域熔炼提纯超高纯锗[J]. 广州化工, 2019, 47(17): 88-90. doi:10.1023/a:1010650624155