logo

颗粒增强钛基复合材料构型化复合研究进展

材料科学与工程

颗粒增强钛基复合材料构型化复合研究进展

劭鹏
晓东
美琦
远飞
维洁
向明
中国有色金属学报第34卷, 第11期pp.3563-3582纸质出版 2024-11-28
9600

近年来以空天飞行器为代表的国家重大战略装备蓬勃发展,对轻质、高强钛基复合材料(TMCs)的需求呈高速增长趋势,并促使其向高性能化方向发展。在复合化的基础上“师法自然”,对组织进行构型化设计是提高钛基复合材料综合性能的有效途径。构型化组织中软硬相间的变形协调作用与异质变形诱导的强化和应变硬化效应能够显著提升材料的加工硬化能力,并获得理想的强塑性协同效果。本文围绕材料研制的各个环节,从基元复合技术、构型化复合工艺途径、组织特征与力学性能等方面综述了钛基复合材料构型化复合的研究现状,深入讨论了构型化组织的共性特征与强韧化机理,总结了目前研究存在的问题与技术难点,并指出钛基复合材料构型化复合的未来发展方向。

钛基复合材料构型化复合微观组织力学性能强韧化机理
REFERENCES
1HAYAT M D, SINGH H, HE Z, et al. Titanium metal matrix composites: An overview[J]. Composites Part A: Applied Science and Manufacturing, 2019, 121: 418-438. doi:10.1023/a:1010650624155
2韩远飞, 乐建温, 方旻翰, 等. 高性能原位自生钛基复合材料制备加工与航天应用探索[J]. 中国材料进展, 2020, 39(12): 945-954. doi:10.1023/a:1010650624155
3吕维洁, 郭相龙, 王立强, 等. 原位自生非连续增强钛基复合材料的研究进展[J]. 航空材料学报, 2014, 34(4): 139-146. doi:10.1023/a:1010650624155
4张长江, 张树志, 侯赵平, 等. (TiBw+TiCp)/Ti复合材料的高温拉伸力学行为与失效机理[J]. 中国有色金属学报, 2016, 26(11): 2287-2295. doi:10.1023/a:1010650624155
5黄陆军, 耿 林, 彭华新. 钛合金与钛基复合材料第二相强韧化[J]. 中国材料进展, 2019, 38(3): 214-222, 250. doi:10.1023/a:1010650624155
6HUANG L J, GENG L, PENG H X. Microstructurally inhomogeneous composites: Is a homogeneous reinforcement distribution optimal?[J]. Progress in Materials Science, 2015, 71: 93-168. doi:10.1023/a:1010650624155
7BARTHELAT F. Biomimetics for next generation materials[J]. Philosophical Transactions of the Royal Society of London, 2007, 365(1861): 2907-2919. doi:10.1023/a:1010650624155
8BARTHELAT F. Nacre from mollusk shells: A model for high-performance structural materials[J]. Bioinspiration and Biomimetics, 2010, 5(3): 035001. doi:10.1023/a:1010650624155
9HUANG L J, AN Q, GENG L, et al. Multiscale architecture and superior high-temperature performance of discontinuously reinforced titanium matrix composites[J]. Advanced Materials, 2021, 33(6): e2000688. doi:10.1023/a:1010650624155
10ZHU Y T, WU X L. Heterostructured materials[J]. Progress in Materials Science, 2023, 131: 101019. doi:10.1023/a:1010650624155
11MAURICE D, COURTNEY T H. Modeling of mechanical alloying: Part Ⅰ. Deformation, coalescence, and fragmentation mechanisms[J]. Metallurgical and Materials Transactions A, 1994, 25(1): 147-158. doi:10.1023/a:1010650624155
12邹正光, 李金莲, 陈寒元. 高能球磨在复合材料制备中的应用[J]. 桂林工学院学报, 2002, 22(2): 174-178. doi:10.1023/a:1010650624155
13王尔德, 胡连喜, 李小强. 高能球磨Ti/Al复合粉体的反应烧结致密行为[J]. 粉末冶金技术, 2003, 21(5): 259-263. doi:10.1023/a:1010650624155
14黄陆军, 耿 林, 等. 网状结构钛基复合材料[M]. 北京: 国防工业出版社, 2014.HUANG L J, GENG L, et al. Titanium matrix composites with network microstructure[M]. Beijing: National Defense Industry Press, 2014. doi:10.1023/a:1010650624155
15HUANG L J, GENG L, WANG B, et al. Effects of volume fraction on the microstructure and tensile properties of in situ TiBw/Ti6Al4V composites with novel network microstructure[J]. Materials & Design, 2013, 45: 532-538. doi:10.1023/a:1010650624155
16黄陆军. 增强体准连续网状分布钛基复合材料研究[D]. 哈尔滨: 哈尔滨工业大学, 2010.HUANG L J. Study on titanium matrix composites with quasi-continuous network distribution of reinforcement[D]. Harbin: Harbin Institute of Technology, 2010. doi:10.1023/a:1010650624155
17SUN F B, HUANG L J, ZHANG R, et al. In-situ synthesis and superhigh modulus of network structured TiC/Ti composites based on diamond-Ti system[J]. Journal of Alloys and Compounds, 2020, 834: 155248. doi:10.1023/a:1010650624155
18HUANG L J, WANG S, GENG L, et al. Low volume fraction in situ (Ti5Si3+Ti2C)/Ti hybrid composites with network microstructure fabricated by reaction hot pressing of Ti-SiC system[J]. Composites Science and Technology, 2013, 82: 23-28. doi:10.1023/a:1010650624155
19SHANG C Y, ZHANG F M, ZHANG B, et al. Interface microstructure and strengthening mechanisms of multilayer graphene reinforced titanium alloy matrix nanocomposites with network architectures[J]. Materials & Design, 2020, 196: 109119. doi:10.1023/a:1010650624155
20MUNIR K S, LI Y C, LIANG D, et al. Effect of dispersion method on the deterioration, interfacial interactions and re-agglomeration of carbon nanotubes in titanium metal matrix composites[J]. Materials & Design, 2015, 88: 138-148. doi:10.1023/a:1010650624155
21MU X N, CAI H N, ZHANG H M, et al. Size effect of flake Ti powders on the mechanical properties in graphene nanoflakes/Ti fabricated by flake powder metallurgy[J]. Composites Part A: Applied Science and Manufacturing, 2019, 123: 86-96. doi:10.1023/a:1010650624155
22HUO W T, LEI C X, DU Y, et al. Superior strength-ductility synergy of (TiC+Ti5Si3)/Ti composites with nacre-inspired architecture[J]. Composites Part B: Engineering, 2022, 240: 109991. doi:10.1023/a:1010650624155
23LEI C X, DU Y, ZHU M, et al. Microstructure and mechanical properties of in situ TiC/Ti composites with a laminated structure synthesized by spark plasma sintering[J]. Materials Science and Engineering A, 2021, 812: 141136. doi:10.1023/a:1010650624155
24ZHANG F M, WANG J, LIU T F, SHANG C Y. Enhanced mechanical properties of few-layer graphene reinforced titanium alloy matrix nanocomposites with a network architecture[J]. Materials & Design, 2020, 186: 108330. doi:10.1023/a:1010650624155
25魏子超, 韩远飞, 李劭鹏, 等. 非连续纳米相增强钛基复合材料研究进展与展望[J]. 航空制造技术, 2022, 65(16): 104-125. doi:10.1023/a:1010650624155
26LI S F, CUI J Y, YANG L F, et al. In situ growth of carbon nanotubes on Ti powder for strengthening of Ti matrix composite via nanotube-particle dual morphology[J]. Metallurgical and Materials Transactions A, 2020, 51(11): 5932-5944. doi:10.1023/a:1010650624155
27LIU Y, LI S F, MISRA R D K, et al. Planting carbon nanotubes within Ti-6Al-4V to make high-quality composite powders for 3D printing high-performance Ti-6Al-4V matrix composites[J]. Scripta Materialia, 2020, 183: 6-11. doi:10.1023/a:1010650624155
28YOLTON C F. The pre-alloyed powder metallurgy of titanium with boron and carbon additions[J]. JOM, 2004, 56(5): 56-59. doi:10.1023/a:1010650624155
29FANG M H, HAN Y F, SHI Z S, et al. Embedding boron into Ti powder for direct laser deposited titanium matrix composite: microstructure evolution and the role of nano-TiB network structure[J]. Composites Part B: Engineering, 2021, 211: 108683. doi:10.1023/a:1010650624155
30LI S P, HAN Y F, WANG X Y, et al. Novel strategy of planting nano-TiB fibers with ultra-fine network distribution into Ti-composite powder and its thermal transition mechanism[J]. Composites Communications, 2022, 29: 101002. doi:10.1023/a:1010650624155
31LI S P, WANG X Y, WEI Z C, et al. Simultaneously improving the strength and ductility of the as-sintered (TiB+La2O3)/Ti composites by in-situ planting ultra-fine networks into the composite powder[J]. Scripta Materialia, 2022, 218: 114835. doi:10.1023/a:1010650624155
32CHEN J J, HAN Y F, LI S P, et al. Evading the strength and ductility trade-off dilemma in titanium matrix composites through designing bimodal grains and micro-nano reinforcements[J]. Scripta Materialia, 2023, 235: 115625. doi:10.1023/a:1010650624155
33李 赞. 仿生构型石墨烯/铝基复合材料制备与性能研究[D]. 上海: 上海交通大学, 2017.LI Z. Preparation and properties of biomimetic graphene/aluminum matrix composites[D]. Shanghai: Shanghai Jiao Tong University, 2017. doi:10.1023/a:1010650624155
34HAN Y F, DUAN H Q, LU W J, et al. Fabrication and characterization of laminated Ti-(TiB+La2O3)/Ti composite[J]. Progress in Natural Science: Materials International, 2015, 25(5): 453-459. doi:10.1023/a:1010650624155
35DUAN H Q, HAN Y F, LU W J, et al. Configuration design and fabrication of laminated titanium matrix composites[J]. Materials & Design, 2016, 99: 219-224. doi:10.1023/a:1010650624155
36黄陆军, 耿 林. 非连续增强钛基复合材料研究进展[J]. 航空材料学报, 2014, 34(4): 126-138. doi:10.1023/a:1010650624155
37WU H D, HAN Y F, HUANG G F, et al. Configuration of new fiber-like structure driven high matching of strength-ductility in TiB reinforced titanium matrix composites[J]. Composites Part B: Engineering, 2022, 231: 109564. doi:10.1023/a:1010650624155
38WU H D, HAN Y F, LE J W, et al. Enhanced strength-ductility synergy in fiber-like structural titanium matrix composites by controlling TiB content[J]. Journal of Alloys and Compounds, 2022, 915: 165399. doi:10.1023/a:1010650624155
39WU H D, LI S P, HAN Y F, et al. Understanding the confined TiB fiber-like structure for strength-ductility combination of discontinuous-reinforced titanium matrix composites[J]. Materials Science and Engineering A, 2022, 852: 143645. doi:10.1023/a:1010650624155
40MU X N, ZHANG H M, CHEN P W, et al. Achieving high performance in graphite nano-flakes reinforced titanium matrix composites through a novel reaction interface design[J]. Carbon, 2021, 175: 334-351. doi:10.1023/a:1010650624155
41LIU X, LIU Z, LIU Y, et al. Achieving high strength and toughness by engineering 3D artificial nacre-like structures in Ti6Al4V-Ti metallic composite[J]. Composites Part B: Engineering, 2022, 230: 109552. doi:10.1023/a:1010650624155
42HUO W T, LEI C X, DU Y, et al. Superior strength-ductility synergy of (TiC+Ti5Si3)/Ti composites with nacre-inspired architecture[J]. Composites Part B: Engineering, 2022, 240: 109991. doi:10.1023/a:1010650624155
43LIU B X, HUANG L J, GENG L, et al. Gradient grain distribution and enhanced properties of novel laminated Ti-TiBw/Ti composites by reaction hot-pressing[J]. Materials Science and Engineering A, 2014, 595: 257-265. doi:10.1023/a:1010650624155
44HUANG L J, GENG L, LI A B, et al. In situ TiBw/Ti-6Al-4V composites with novel reinforcement architecture fabricated by reaction hot pressing[J]. Scripta Materialia, 2009, 60(11): 996-999. doi:10.1023/a:1010650624155
45HUANG L J, GENG L, PENG H X, et al. Room temperature tensile fracture characteristics of in situ TiBw/Ti6Al4V composites with a quasi-continuous network architecture[J]. Scripta Materialia, 2011, 64(9): 844-847. doi:10.1023/a:1010650624155
46HUANG L J, GENG L, PENG H X, et al. Effects of sintering parameters on the microstructure and tensile properties of in situ TiBw/Ti6Al4V composites with a novel network architecture[J]. Materials & Design, 2011, 32(6): 3347-3353. doi:10.1023/a:1010650624155
47HUANG L J, WANG S, DONG Y S, et al. Tailoring a novel network reinforcement architecture exploiting superior tensile properties of in situ TiBw/Ti composites[J]. Materials Science and Engineering A, 2012, 545: 187-193. doi:10.1023/a:1010650624155
48HUANG L J, GENG L, PENG H X, et al. High temperature tensile properties of in situ TiBw/Ti6Al4V composites with a novel network reinforcement architecture[J]. Materials Science and Engineering A, 2012, 534: 688-692. doi:10.1023/a:1010650624155
49HUANG L J, XU H Y, WANG B, et al. Effects of heat treatment parameters on the microstructure and mechanical properties of in situ TiBw/Ti6Al4V composite with a network architecture[J]. Materials & Design (1980-2015), 2012, 36: 694-698. doi:10.1023/a:1010650624155
50HUANG L J, GENG L, XU H Y, et al. In situ TiC particles reinforced Ti6Al4V matrix composite with a network reinforcement architecture[J]. Materials Science and Engineering A, 2011, 528(6): 2859-2862. doi:10.1023/a:1010650624155
51HUANG L J, GENG L, FU Y, et al. Oxidation behavior of in situ TiCp/Ti6Al4V composite with self-assembled network microstructure fabricated by reaction hot pressing[J]. Corrosion Science, 2013, 69: 175-180. doi:10.1023/a:1010650624155
52HUANG L J, GENG L, PENG H X. In situ (TiBw+TiCp)/Ti6Al4V composites with a network reinforcement distribution[J]. Materials Science and Engineering A, 2010, 527(24/25): 6723-6727. doi:10.1023/a:1010650624155
53HUANG G F, GUO X L, HAN Y F, et al. Effect of extrusion dies angle on the microstructure and properties of (TiB+TiC)/Ti6Al4V in situ titanium matrix composite[J]. Materials Science and Engineering A, 2016, 667: 317-325. doi:10.1023/a:1010650624155
54WEI S L, HUANG L J, LI X T, et al. Network-strengthened Ti-6Al-4V/(TiC+TiB) composites: Powder metallurgy processing and enhanced tensile properties at elevated temperatures[J]. Metallurgical and Materials Transactions A, 2019, 50(8): 3629-3645. doi:10.1023/a:1010650624155
55焦 阳. 两级网状结构(Ti5Si3+TiBw)/Ti6Al4V复合材料研究[D]. 哈尔滨: 哈尔滨工业大学, 2018.JIAO Y. Study on two-stage network structure (Ti5Si3+TiBw)/Ti6Al4V composites[D]. Harbin: Harbin Institute of Technology, 2018. doi:10.1023/a:1010650624155
56HU H T, HUANG L J, GENG L, et al. Oxidation behavior of TiB-whisker-reinforced Ti60 alloy composites with three-dimensional network architecture[J]. Corrosion Science, 2014, 85: 7-14. doi:10.1023/a:1010650624155
57JIAO Y, HUANG L J, AN Q, et al. Effects of Ti5Si3 characteristics adjustment on microstructure and tensile properties of in-situ (Ti5Si3+TiBw)/Ti6Al4V composites with two-scale network architecture[J]. Materials Science and Engineering A, 2016, 673: 595-605. doi:10.1023/a:1010650624155
58JIAO Y, HUANG L J, WEI S L, et al. Nano-Ti5Si3 leading to enhancement of oxidation resistance[J]. Corrosion Science, 2018, 140: 223-230. doi:10.1023/a:1010650624155
59伍子纯, 刘 阳, 李海尊, 等. 激光增材制造网状结构金属基复合材料的研究进展[J]. 中国有色金属学报, 2024, 34(4): 1052-1070. doi:10.1023/a:1010650624155
60李树丰, 王少迪, 潘 登, 等. 增材制造硼化钛增强钛基复合材料的研究进展[J]. 中国有色金属学报, 2024, 34(4): 1113-1139. doi:10.1023/a:1010650624155
61FANG M H, HAN Y F, SHI Z S, et al. Embedding boron into Ti powder for direct laser deposited titanium matrix composite: microstructure evolution and the role of nano-TiB network structure[J]. Composites Part B: Engineering, 2021, 211: 108683. doi:10.1023/a:1010650624155
62刘化强, 王治涵, 冯姝慧, 等. 激光熔化沉积原位制备三维网状Ti6Al4V基复合材料的组织与力学性能[J]. 中国有色金属学报, 2023, 33(2): 372-385. doi:10.1023/a:1010650624155
63ZHOU Y, WANG K, SUN Z G, et al. Simultaneous improvement of strength and elongation of laser melting deposited Ti-6Al-4V titanium alloy through three-stage heat treatment[J]. Journal of Materials Processing Technology, 2022, 306. doi:10.1023/a:1010650624155
64远 飞, 吴华舵, 吕维洁, 等. 用于制备构型复合材料的限域填粉法: CN202111519447.6[P]. 2023-07-11. . doi:10.1023/a:1010650624155
65JIANG L, LI Z Q, FAN G L, et al. A flake powder metallurgy approach to Al2O3/Al biomimetic nanolaminated composites with enhanced ductility[J]. Scripta Materialia, 2011, 65(5): 412-415. doi:10.1023/a:1010650624155
66MU X N, CHEN P W, ZHANG H M, et al. Interface-dependent failure behaviors in graphene nanoflakes reinforced Ti matrix composites[J]. Materials Letters, 2021, 289: 129422. doi:10.1023/a:1010650624155
67MU X N, CAI H N, ZHANG H M, et al. Uniform dispersion and interface analysis of nickel coated graphene nanoflakes/ pure titanium matrix composites[J]. Carbon, 2018, 137: 146-155. doi:10.1023/a:1010650624155
68LIU L, LI Y K, ZHANG H M, et al. Enhanced strain-hardening capability in graphene nanoplatelets reinforced Ti composites through tailoring a novel three-dimensional interface structure[J]. Composites Part A: Applied Science and Manufacturing, 2022, 156: 106892. doi:10.1023/a:1010650624155
69LIU L, LI Y K, ZHANG H M, et al. Reaction kinetics of three-dimensional interface in graphene nanoplatelets reinforced titanium (GNPs/Ti) composites as revealed by in situ TEM heating experiments[J]. Composites Part B: Engineering, 2022, 247: 110237. doi:10.1023/a:1010650624155
70LIU L, LI Y K, ZHANG H M, et al. Breaking through the dynamic strength-ductility trade-off in TiB reinforced Ti composites by incorporation of graphene nanoplatelets[J]. Composites Part B: Engineering, 2022, 230: 109499. doi:10.1023/a:1010650624155
71LIU L, LI Y K, ZHANG H M, et al. Simultaneously enhancing strength and ductility in graphene nanoplatelets reinforced titanium (GNPs/Ti) composites through a novel three-dimensional interface design[J]. Composites Part B: Engineering, 2021, 216: 108851. doi:10.1023/a:1010650624155
72LI S P, WANG X Y, LE J W, et al. Towards high strengthening efficiency by in-situ planting nano-TiB networks into titanium matrix composites[J]. Composites Part B: Engineering, 2022, 245: 110169. doi:10.1023/a:1010650624155
73CHEN J J, HAN Y F, WEI Z C, et al. Heterostructured titanium composites with superior strength-ductility synergy via controllable bimodal grains and 〈c+a〉 dislocation activity[J]. Materials Research Letters, 2023, 11(10): 863-871. doi:10.1023/a:1010650624155
74LIU L, LI S F, PAN D, et al. Loss-free tensile ductility of dual-structure titanium composites via an interdiffusion and self-organization strategy[J]. Proceedings of the National Academy of Sciences of the United States of America, 2023, 120(28): e2302234120. doi:10.1023/a:1010650624155
75WANG S, HUANG L J, AN Q, et al. Strength-ductility synergy of in-situ TiB/Ti6Al4V composites with tailored hierarchical TiB distributions[J]. Ceramics International, 2022, 48(23): 35069-35075. doi:10.1023/a:1010650624155
76ZHU Y T, AMEYAMA K, ANDERSON P M, et al. Heterostructured materials: superior properties from hetero-zone interaction[J]. Materials Research Letters, 2021, 9(1): 1-31. doi:10.1023/a:1010650624155
77HUANG C X, WANG Y F, MA X L, et al. Interface affected zone for optimal strength and ductility in heterogeneous laminate[J]. Materials Today, 2018, 21(7): 713-719. doi:10.1023/a:1010650624155